I suggest you to use MVC Training kit and use lab exercises while you learn.

Doing hands on while learning will increase the efficiency by 70%, and that would be the nice and interesting way to learn new concepts.

Please find the Training kit link below for ASP.NET MVC

http://trainingkit.webcamps.ms/AspNetMvc.htm

Simultaneously, refer the http://www.asp.net/mvc link, to reach the complete efficiency level of learning.