private bool CreateConnection()
        {
            try
            {
                con = new LdapConnection(new LdapDirectoryIdentifier(ConfigurationSettings.AppSettings["ServerName"].ToString()));
                con.SessionOptions.SecureSocketLayer = true;
                con.SessionOptions.ProtocolVersion = 3;
                con.SessionOptions.VerifyServerCertificate = new VerifyServerCertificateCallback(ServerCallback);
                con.Credential = new NetworkCredential(_domainAndUserName, _pwd);
                con.AuthType = AuthType.Basic;
                con.Timeout = new TimeSpan(1, 0, 0);
                return true;
            }
            catch (LdapException)
            {
                return false;
            }
            catch (Exception)
            {
                return false;
            }
        }


 public bool ServerCallback(LdapConnection connection, X509Certificate certificate)
        {
...return true/false;
}
 public bool LDAPSAuthenticate(String username, String pwd)
        {
            username = username.Trim();
            try
            {
                con.Bind();
            }
            catch (LdapException ex)
            {
                throw new LdapException(ex.Message);
            }
            catch (DirectoryOperationException ex)
            {
                throw new DirectoryOperationException(ex.Message);
            }


            try
            {
                SearchRequest request = new SearchRequest(
                    UsersDN,
                    "(&(objectClass=person)(SAMAccountName=" + username + "))",
                    System.DirectoryServices.Protocols.SearchScope.Subtree
                    );




                SearchResponse response = (SearchResponse)con.SendRequest(request);




                if (response.Entries.Count == 0)
                {
                    return false;
                }
                else
                {
                    SearchResultEntry entry = response.Entries[0];
                    string dn = entry.DistinguishedName;


                    con.Credential = new NetworkCredential(dn, pwd);
                    con.Bind();
                    return true;
                }
            }
            catch (DirectoryOperationException ex)
            {
                throw new DirectoryOperationException(ex.Message);
            }


            catch (LdapException ex)
            {
                throw new LdapException(ex.Message);
            }
            catch (Exception ex)
            {
                throw new LdapException(ex.Message);
            }
        }

I have used the above code and it is working fine for LDAP using SSL.  Please let me know if you need more information

<div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste"> public bool LDAPSAuthenticate(String username, String pwd)</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">        {</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            username = username.Trim();</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            try</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            {</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                con.Bind();</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            }</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            catch (LdapException ex)</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            {</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                throw new LdapException(ex.Message);</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            }</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            catch (DirectoryOperationException ex)</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            {</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                throw new DirectoryOperationException(ex.Message);</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            }</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste"></div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            try</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            {</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                SearchRequest request = new SearchRequest(</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                    UsersDN,</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                    "(&(objectClass=person)(SAMAccountName=" + username + "))",</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                    System.DirectoryServices.Protocols.SearchScope.Subtree</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                    );</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste"></div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste"></div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                SearchResponse response = (SearchResponse)con.SendRequest(request);</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste"></div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste"></div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                if (response.Entries.Count == 0)</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                {</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                    return false;</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                }</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                else</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                {</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                    SearchResultEntry entry = response.Entries[0];</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                    string dn = entry.DistinguishedName;</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste"></div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                    con.Credential = new NetworkCredential(dn, pwd);</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                    con.Bind();</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                    return true;</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                }</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            }</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            catch (DirectoryOperationException ex)</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            {</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                throw new DirectoryOperationException(ex.Message);</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            }</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste"></div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            catch (LdapException ex)</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            {</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                throw new LdapException(ex.Message);</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            }</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            catch (Exception ex)</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            {</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">                throw new LdapException(ex.Message);</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">            }</div> <div style="position: absolute; left: -10000px; top: 0px; width: 1px; height: 1px; overflow-x: hidden; overflow-y: hidden;" id="_mcePaste">        }</div>