You can use the query given by andrewjboyd;
select * from <specify your table name here> where CheckOut <= GetDate() or ChechkOut is null
by which you will get the details of the room which are not available[already booked], the
"getdate function will get you the current date."
think u dont need more explanations.
just do this query to understand getdate ()
select getdate(), if you want only the datepart then do
Select convert(varchar, getdate(), 105)