Hi Donetcoder08,
I think your description is not so clear, and I can not fully understand what you really want to do.
Based on my understanding , you can to convert that row to editmode and find the radiobuttonlist in edittemplate and restore it's selectedvalue to the value stored in session.
You code above may be wrong. Because you only set GridView1.EditIndex = GVR.RowIndex and this is not enough.
Usually, you need to do some steps below to make that row to edit mode
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set editindex just like GridView1.EditIndex = GVR.RowIndex
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set gridview's datasource (or you connect the gridview to one datasource control , you can omit this step)
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invoke gridview's DataBind method.