Ah, we're getting warmer. Unfortunately I don't have any {C68EA39B-DC7B-472b-B0EC-68DB0603AB94} editor there, probably because this is studio 8.0, not 9.0. The only ones that mention SQL are:
{E1F86ED4-287D-48b1-A159-92FF1C86B40B} - SQLMobile File Handler (extension .MDF)
{29887BCD-E81F-4722-85CE-2CCF2D9AF30A} - SQL Data File Handler (extension .SDF)
Neither sounds like an SQL source file editor. And yet such an editor does apparently exist, as it highlights standard SQL keywords, though not the Oracle proprietary ones.
Nearby I found HKEY_LOCAL_MACHINE\SOFTWARE\Microsoft\VisualStudio\8.0\Languages\File Extensions ... this may be where the magic happens. In there's a key for .sql that has one value: (Default) = {FA6E5E79-C8EE-4D37-B79A-5067F8BD5630}. That appears to be a reference to HKEY_LOCAL_MACHINE\SOFTWARE\Microsoft\VisualStudio\8.0\Services\{FA6E5E79-C8EE-4D37-B79A-5067F8BD5630}, which is also referenced by HKEY_LOCAL_MACHINE\SOFTWARE\Microsoft\VisualStudio\8.0\Languages\Language Services\T-SQL. So, it looks like if I find the guid under HKEY_LOCAL_MACHINE\SOFTWARE\Microsoft\VisualStudio\8.0\Languages\Language Services\PL/SQL, which is {0007B8F0-3435-46BB-BF59-1D3652E6B7A2}, then I can create new extensions pointing to that.
...
IT WORKED! It highlights things like "create or replace synonym" now.